Isospin is another way of thinking about the two types of nucleons. It has proved quite useful in understanding nuclei, as well as elementary particles.
Normally, you think of nuclei as consisting of protons and neutrons. But protons and neutrons are very similar in properties, if you ignore the Coulomb force. They have almost the same mass. Also, according to charge independence, the nuclear force is almost the same whether it is protons or neutrons.
So suppose you define only one particle, called nucleon. Then you can
give that particle an additional property called “nucleon
type.” If the nucleon type is
,
it is a neutron. That makes
nucleon type a property that is mathematically much like the spin
of a nucleon in a chosen
-
,
,
| (14.40) |
So far, all this it may seem like a stupid mathematical trick. And normally it would be. The purpose of mathematical analysis is to understand systems, not to make them even more incomprehensible.
But to the approximation that the nuclear force is charge-independent,
nucleon type is not so stupid after all. If the nuclear force is
charge-independent, and the Coulomb force is ignored, you can write
down nuclear wave functions without looking at the nucleon type. Now
suppose that in doing so, you find some energy eigenfunction of the
form
That is fine if nucleon 1 is a proton and nucleon 2 a neutron. Or vice-versa. But it is not OK if both nucleons are protons, or if they are both neutrons. Wave functions must change sign if two identical fermions are exchanged. That is the antisymmetrization requirement. The wave function above stays the same. So it is only acceptable for the deuteron, with one proton and one neutron.
Next suppose you could find a different wave function of the form
That would give nontrivial insight in nuclear energy levels. It would
mean physically that the diproton, the dineutron, and the deuteron can
be in an identical energy state. Such identical energy states,
occurring for different nuclei, are called “isobaric analog (or analogue) states.” Or “charge states.” Or “isobaric multiplets.” Or “
-
Disappointingly, in real life there is no bound state of the form
.
Within the approximations of charge independence and negligible Coulomb effects, whether a given state applies to a given set of nucleon types depends only on the antisymmetrization requirements.Now for bigger systems of nucleons, the antisymmetrization requirements get much more complex. A suitable formalism for dealing with that has already been developed in the context of the spin of systems of identical fermions. It is convenient to adopt that formalism also for nucleon type.
As an example, consider the above three hypothetical isobaric analog
states for the diproton, dineutron, and deuteron. They can be written
out separately as, respectively,

The third wave function represents something of a change in thinking. It requires that one nucleon is a proton and the other a neutron. So it is a wave function for the deuteron. But the actual wave function above is a superposition of two states. In the first state, nucleon 1 is the proton and nucleon 2 the neutron. In the second state, nucleon 1 is the neutron and nucleon 2 the proton. In the combined state the nucleons have lost their identity. It is uncertain whether nucleon 1 is the proton and nucleon 2 the neutron, or vice-versa.
Within the formalism of identical nucleons that have an additional nucleon-type property, this uncertainty in nucleon types is unavoidable. The wave function would not be antisymmetric under nucleon exchange without it. But if you think about it, this may actually be an improvement in the description of the physics. Protons and neutrons do swap identities. That happens if they exchange a charged pion. Proton-neutron scattering experiments show that they can do that. For nucleons that have a probability of swapping type, assigning a fixed type in energy eigenstates is not right. Energy eigenstates must be stationary. And having a better description of the physics can affect what sort of potentials you would want to write down for the nucleons.
(You might think that without charge independence, the additional
antisymmetrization requirement for identical nucleons would change the
physics. But actually, it does not. The antisymmetrization
requirement can be accomodated by uncertainty in which nucleon you
label 1 and which 2. Consider some completely general proton-neutron
wave function
,
Now compare the trailing nucleon-type factors in the three
hypothetical isobaric analog states above with the possible combined
spin states of two spin
fermions. It is seen that the
nucleon-type factors take the exact same form as the so-called
“triplet” spin states, (5.26). So define
similarly
![]() |
(14.42) |
Now reconsider the wave function for two nucleons that was written
down first. The one that was only acceptable for the deuteron. In
the same terminology, it can be written as
Of course, all this raises the question what to make of the leading 0
in the singlet state
,
?
of the square spin
angular momentum. Square spin angular momentum is the sum of the
square spin components in the
,
,
directions. But at first that seems to make no sense for nucleon
type. Nucleon type is just a simple number, not a vector. While it
has been formally associated with some abstract 3-axis, there are no
“
” and “
” components.
However, it is possible to define such components in complete analogy
with the
and
components of spin. In quantum mechanics the
components of spin are the eigenvalues of operators. And using
advanced concepts of angular momentum, chapter 12, the
operators of
and
angular momenta can be found without
referring explicitly to their axes. The same procedure can be
followed for nucleon type.
To do so, first an operator
for the nucleon type
is
defined as
| (14.43) |
Next a “charge creation operator” is defined by
| (14.44) |
| (14.45) |
| (14.46) |
With these operators, square nucleon type can be defined just like square spin. All the mathematics has been forced to be the same.
The quantum number of square nucleon type will be indicated by
in this book. Different sources use different notations. Many
sources swap case, using lower case for the operators and upper case
for the quantum numbers. Or they use lower case if it is for a single
nucleon and upper case for the entire nucleus. They often do the same
for angular momentum. Some sources come up with
for the square
nucleon type quantum number, using
for the angular momentum one.
However, this book cannot adopt completely inconsistent notations just
for nuclear physics. Especially if there is no generally agreed-upon
notation in the first place.
In any case there are three scaled operators whose definition and
symbols are fairly standard in most sources. These are defined as
| (14.47) |
Now consider an example of isobaric analog states that actually exist. In this case the nucleons involved are carbon-14, nitrogen-14, and oxygen-14. All three have 14 nucleons, so they are isobars. However, carbon-14 has 6 protons and 8 neutrons, while oxygen-14 has 8 protons and 6 neutrons. Such pairs of nuclei, that have their numbers of protons and neutrons swapped, are called “conjugate” nuclei. Or “mirror” nuclei. Nitrogen-14 has 7 protons and 7 neutrons and is called “self-conjugate.”
Since
values add up, carbon-14 with 6 protons at
each
and 8 neutrons at
each has net
1
0, as any self-conjugate nucleus,
while oxygen-14 has
1. In general,
In general, 14 nucleons can have a maximum
7, if all 14 are
protons. The minimum is
7
Here is where the analogy with spin angular momentum gets interesting.
Angular momentum is a vector. A given angular momentum vector can
still have different directions. And different directions means
different values of the
-
.
components are
Since nucleon type has been defined to be completely equivalent to
spin, essentially the same holds. A given nucleon energy state can
still have different values of
:
| (14.49) |
You could say that isobaric analog states arise because “rotating” an energy state in the abstract 1,2,3-space defined above does not make a difference. And the reason it does not make a difference is charge independence.
Based on the values of
above, consider the possible values of
for 14 nucleons. The value of
cannot be greater than 7.
Otherwise there would be isobaric analog states with
greater
than 7, and that is not possible for 14 nucleons. As far as the
lowest possible value of
is concerned, it varies with nucleus.
As the expression above shows, the value of
cannot be greater
than
.
cannot be less than
.
1, for these nuclei,
cannot be less than 1. However, nitrogen-14, with
0, also
allows states with
0.
It turns out that light nuclei in their ground state generally have
the smallest value of
consistent with their value of
.
7 for 14 nucleons allows the state
7, in which
all 14 nucleons are protons. In that state, the wave function must be
antisymmetric when any nucleon is interchanged with any other. On the
other hand, a
0 state only needs to satisfy the
antisymmetrization requirements for 7 protons and 7 neutrons. It does
not have to be antisymmetric if a proton is exchanged with any one of
the 7 neutrons. So antisymmetrization is less confining. In general,
a state with
greater than
must work for more nuclei than
one with
.
(Another argument, offered in literature, is essentially the reverse
of the one that gives rise to the so-called “Hund rule”
for atoms. Simply put, the Hund rule says that a couple of electrons
maximize their spin, given the option between single-particle states
of the same energy. The reason is that this allows electrons to stay
farther apart, reducing their Coulomb repulsion,
{D.56}. This argument reverses for nucleons, since
they normally attract rather than repel each other. However, surely
this is a relatively minor effect? Consider 3 nucleons. For these,
the highest value
allows the possibility that all 3
are protons. Within a single-particle-state picture, only one can go
into the lowest energy state; the second must go into the second
lowest energy state, and the third in the third lowest. On the other
hand, for say 2 protons and 1 neutron, the neutron can go into the
lowest energy state with the first proton. So the lower value
should normally have significantly less energy.)
For the deuteron
0, so the lowest possible value of
is
0. Then according to the general rule above, the ground state of the
deuteron should have
0. That was already established above;
it was the bound state not shared with the diproton and dineutron.
Nitrogen-14 also has
0, which means it too must have
0
in its ground state. This lowest energy state cannot occur for
carbon-14 or oxygen-14, because they have
1. So nitrogen-14
should have less energy in its ground state than carbon-14 and
oxygen-14. That seems at first surprising since nitrogen-14 has odd
numbers of protons and neutrons, while carbon-14 and oxygen-14 have
even numbers. Normally odd-odd nuclei are less tightly bound than
even-even ones.
But it is true. Figure 14.44 shows the energy levels of carbon-14, nitrogen-14, and oxygen-14. More precisely, it shows their binding energy, relative to the ground state value for nitrogen-14. In addition the von Weizsäcker value for the Coulomb energy has been subtracted to more clearly isolate the nuclear force effects. (The net effect is simply to shift the normal spectra of carbon-14 and oxygen-14 up by 2.83, respectively 1.89 MeV.) It is seen that nitrogen-14 is indeed more tightly bound in its ground state than carbon-14 and oxygen-14. Qualitatively, since nitrogen-14 does not have 8 nucleons of the same kind, it has an easier job with satisfying the antisymmetrization requirements.
Traces of the lower energy of light nuclei with
0 can also
be detected in figures like 14.2, and 14.3
through 14.6. In these figures
0 straight
above the
2 helium nucleus. Note in particular a
distinct dark/light discontinuity in figures 14.3 through
14.6 along this vertical line. This discontinuity is quite
distinct both from the magic numbers and from the average stability
line that curves away from it.
Carbon-14 and oxygen-14 are mirror nuclei, so you would expect them to
have pretty much the same sort of energy levels. Indeed, any
oxygen-14 state, having
1, must be part of a multiplet with
at least 1. Such a multiplet must have an equivalent state with
1![]()
1, the
smallest possible.
Now each of these multiplets should also have a version with
0, which means a nitrogen-14 state. So any state that carbon-14 and
oxygen-14 have should also exist for nitrogen-14. For example, the
ground states of carbon-14 and oxygen-14 should also appear as a ![]()
1 in the nitrogen-14 spectrum. Indeed, if you
inspect the energy levels for nitrogen-14 in figure
14.44, exactly halfway in between the carbon-14 and
oxygen-14 ground state energies, there it is!
Ideally speaking, these three states should have the same height in the figure. But it would be difficult to remove the Coulomb effect completely. And charge independence is not exact either, even though it is quite accurate.
A similar
0 state can readily be found for the first three
excited levels of carbon-14 and oxygen-14. In each case there is a
nitrogen-14 state with exactly the same spin and parity and
1
right in between the matching carbon-14 and oxygen-14 levels. (To be
sure, ENSDF does not list the
values for carbon-14 above the
ground state. But common sense says they must be the same as the
corresponding states in nitrogen-14 and carbon-14. For the first
excited state of carbon-14, this is confirmed in
[48, p. 11].)
Figure 14.44 also shows that nitrogen-14 has a lot more
low energy states than carbon-14 or oxygen-14. Square nucleon type
can explain that too: all the low-lying states of nitrogen-14 that are
not shared with carbon-14 and oxygen-14 are
0 states. These
states are not possible for the other two nuclei.
Nothing is perfect, of course. The first state with nonzero
in
the nitrogen spectrum besides the mentioned four isobaric analog
states is the ![]()
1 state at 8.8 MeV, just below the ![]()
![]()
![]()
Despite such imperfections, consideration of nucleon type is quite helpful for understanding the energy levels of light nuclei. And a lot of it carries over to heavier nuclei, [48, p. 12] and [34, p. 57]. While heavier nuclei have significant Coulomb energy, this long-range force is apparently often not that important here.
Now all that is needed is a good name. “Nucleon type” or “nucleon class” are not acceptable; they would give those hated outsiders and pesky students a general idea of what physicists were talking about. However, physicists noted that there is a considerable potential for confusion between nucleon type and spin, since both are described by the same mathematics. To maximize that potential for confusion, physicists decided that nucleon type should be called “spin.”
Of course, physicists themselves still have to know whether they are
talking about nucleon type or spin. Therefore some physicists called
nucleon type “isobaric spin,” because what
differentiates isobars is the value of the net
.
for the proton, others for the neutron. However, that confused
physicists themselves, so eventually it was decided that the proton
has
.
Isospin is conserved when only the nuclear force is relevant. As an
example, consider the reaction in which a deuteron kicks an alpha
particle out of an oxygen-16 nucleus:
Selection rules for which nuclear decays occur can also be formulated
based on isospin. If the electromagnetic force plays a significant
part,
but not
is conserved. The weak force does not
conserve
either, as beta decay shows. For example, the ground
states of oxygen-14 and carbon-14 in figure 14.44 will
beta-decay to the ground state of nitrogen 14, changing both
and
.
Despite the lack of isospin conservation, isospin turns out to be very useful for understanding beta and gamma decay. See for example the discussion of superallowed beta decays in chapter 14.19, and the isospin selection rules for gamma decay in section 14.20.2.
There are other particles besides nucleons that are also pretty much
the same except for electric charge, and that can also be described
using isospin. For example, the positive, neutral, and negatively
charged pions form an isospin triplet of states with
1. Isospin
was quite helpful in recognizing the existence of the more basic
particles called quarks that make up baryons like nucleons and mesons
like pions. In final analysis, the usefulness of isospin is a
consequence of the approximate properties of these quarks.
Some sources incorrectly credit the concept of isospin to Heisenberg. But he did not understand what he was doing. Heisenberg did correctly guess that protons and neutrons might be described as two variants of the same particle. He then applied the only quantum approach for a two-state particle to it that he knew, that of spin. However, the mathematical machinery of spin is designed to deal with two-state properties that are preserved under rotations of an axis system, compare {A.19}. That is an inappropriate mathematical approach to describe nucleon type in the absence of charge independence. And at the time Heisenberg himself believed that the nuclear force was far from charge-independent.
(Because the nuclear force is in fact approximately
charge-independent, unlike Heisenberg assumed, isospin is preserved
under rotations of the abstract 1,2,3 coordinate system as defined in
the first subsection. Phrased more simply, without charge
independence, energy eigenfunctions would not have definite values of
square isospin
.
The recognition that isospin was meaningful only in the presence of
charge independence, and the proposal that the nuclear force is indeed
quite accurately
See Wilkinson, [48, p. vi, 1-13], for a more extensive discussion of these historical issues. A very different history is painted by Henley in the next chapter in the same book. In this history, Heisenberg receives all the credit. Wigner does not exist. However, the author of this history implicitly admits that Heisenberg did think that the nuclear force was far from charge-independent. Maybe the author understood isospin too poorly to recognize that that is a rather big problem. Certainly there is no discussion. Or the author had a personal issue with Wigner and was willing to sacrifice his scientific integrity for it. Either way, the credibility of the author of this particular history is zero.
It may seem astonishing that all this works. Why would nucleon type resemble spin? Spin is a vector in three-dimensional space, not a simple number. Why would energy eigenstates be unchanged under rotations in some weird abstract space?
The simplest and maybe best answer is that nature likes this sort of mathematics. Nature just loves creation and annihilation operators. But still, why would that lead to preserved lengths of vectors in an abstract spaces?
An answer can be obtained by looking a bit closer at square spin.
Consider first two spin
fermions. Compare the dot product
of their spins to the operator
that exchanges
their spins:
Comparing the two sets of relations, it is seen that the dot product
of two spins is closely related to the operator that exchanges the two
spins:
Now consider the square spin of a system of
fermions. By definition
Similarly then for isospin as defined in the first subsection,
It may be noted that the exchange operators do not commute among
themselves. That makes the symmetry requirements so messy. However,
it is possible to restrict consideration to exchange operators of the
form
.
Infinitesimal “rotations” of a state in 1,2,3 isospin
state correspond to applying small multiples of the operators
,
and
,
and
,![]()