Question: Verify that the sets of quantum numbers shown in the spectrum figure 2.15 do indeed produce the indicated energy levels.
Answer:
The generic expression for the energy is
Now for the bottom level,
, so
, this state has energy
.
Similarly, in each of the three sets of the second energy level in figure 2.15, the three quantum numbers
,
, and
add up to
, giving this state energy
.
For the third energy level, the three quantum numbers of each set add up to
, giving energy
, and for the fourth set, the quantum numbers in each of the ten sets add up to
for an energy
.